Organic Chemistry · free preview
Chapter 14: Review and Practice
The unsaturated compounds we’ve looked at previously have had only one double bond, but many compounds have numerous sites of unsaturation, which gives them some distinctive properties. Many such compounds are common in nature, including pi
1. The unsaturated compounds we’ve looked at previously have ha
The unsaturated compounds we’ve looked at previously have ha
2. Ultraviolet (UV) spectroscopy is a method of structure deter
Ultraviolet (UV) spectroscopy is a method of structure deter
3. Chemistry Matters — Photolithography
Chemistry Matters — Photolithography
4. The polymer resist currently used in chip manufacturing is b
The polymer resist currently used in chip manufacturing is b
5. Summary of Reactions
Summary of Reactions
6. Additional Problems
Additional Problems
7. Problem 14-20 (a) (b) (c) Problem 14-21 We’ve seen that the
Problem 14-20 (a) (b) (c) Problem 14-21 We’ve seen that the
8. Problem 14-24 A useful diene in the synthesis of many natura
Problem 14-24 A useful diene in the synthesis of many natura
9. Problem 14-28 Electrophilic addition of Br_{\text{2}} to iso
Problem 14-28 Electrophilic addition of Br_{\text{2}} to iso
10. Problem 14-32 2,3-Di-tert-butyl-1,3-butadiene does not under
Problem 14-32 2,3-Di-tert-butyl-1,3-butadiene does not under
11. Problem 14-36 Reaction of isoprene (2-methyl-1,3-butadiene)
Problem 14-36 Reaction of isoprene (2-methyl-1,3-butadiene)
12. Problem 14-40 (a) (b) (c) (d) Problem 14-41 Show the product
Problem 14-40 (a) (b) (c) (d) Problem 14-41 Show the product
13. Problem 14-44 (a) (b) (c) Problem 14-45 (a) (b) (c) Problem
Problem 14-44 (a) (b) (c) Problem 14-45 (a) (b) (c) Problem
14. Problem 14-48 1,3,5-Hexatriene has λ_{\text{max}} = 258 nm.
Problem 14-48 1,3,5-Hexatriene has λ_{\text{max}} = 258 nm.
15. Problem 14-52 Treatment of 3,4-dibromohexane with strong bas
Problem 14-52 Treatment of 3,4-dibromohexane with strong bas
16. Problem 14-56 The triene shown here reacts with 2 equivalent
Problem 14-56 The triene shown here reacts with 2 equivalent
17. Problem 14-60 Ergosterol, a precursor of vitamin D, has λ_{\
Problem 14-60 Ergosterol, a precursor of vitamin D, has λ_{\
18. Problem 14-64 The double bond of an enamine (alkene + amine)
Problem 14-64 The double bond of an enamine (alkene + amine)
19. Key Terms
Key Terms
20. - dienophile - endo - exo - highest occupied molecular orbit
- dienophile - endo - exo - highest occupied molecular orbit
21. - kinetic control - lowest unoccupied molecular orbital (LUM
- kinetic control - lowest unoccupied molecular orbital (LUM
22. - stereospecific - thermodynamic control - ultraviolet (UV)
- stereospecific - thermodynamic control - ultraviolet (UV)
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