Organic Chemistry · free preview
Chapter 17: Review and Practice
In previous chapters, we focused on developing general ideas of organic reactivity, looking at the chemistry of hydrocarbons and alkyl halides and seeing some of the tools used in structural studies. With that accomplished, we have now begu
1. In previous chapters, we focused on developing general ideas
In previous chapters, we focused on developing general ideas
2. Phenols are aromatic counterparts of alcohols but are more a
Phenols are aromatic counterparts of alcohols but are more a
3. Chemistry Matters — Ethanol: Chemical, Drug, and Poison
Chemistry Matters — Ethanol: Chemical, Drug, and Poison
4. Ethanol metabolism occurs mainly in the liver and proceeds b
Ethanol metabolism occurs mainly in the liver and proceeds b
5. Summary of Reactions
Summary of Reactions
6. Additional Problems
Additional Problems
7. Problem 17-24 Name and assign R or S stereochemistry to the
Problem 17-24 Name and assign R or S stereochemistry to the
8. Problem 17-28 Treatment of the following epoxide with aqueou
Problem 17-28 Treatment of the following epoxide with aqueou
9. Problem 17-32 (a) (b) (c) Problem 17-33 (a) (b) (c) Problem
Problem 17-32 (a) (b) (c) Problem 17-33 (a) (b) (c) Problem
10. Problem 17-36 (a) (b) (c) Problem 17-37 (a) (b) (c) (d) (e)
Problem 17-36 (a) (b) (c) Problem 17-37 (a) (b) (c) (d) (e)
11. Problem 17-40 Bombykol, the sex pheromone secreted by the fe
Problem 17-40 Bombykol, the sex pheromone secreted by the fe
12. Problem 17-44 (a) 2-Methyl-2-propanol 2-Methyl-2-propanol (b
Problem 17-44 (a) 2-Methyl-2-propanol 2-Methyl-2-propanol (b
13. Problem 17-48 (a) Acetophenone (PhCOCH_{\text{3}}) cetopheno
Problem 17-48 (a) Acetophenone (PhCOCH_{\text{3}}) cetopheno
14. Problem 17-52 (a) C_{\text{5}}H_{\text{12}}O _{\text{5}}H_{\
Problem 17-52 (a) C_{\text{5}}H_{\text{12}}O _{\text{5}}H_{\
15. Problem 17-56 Propose a structure for a compound C_{\text{15
Problem 17-56 Propose a structure for a compound C_{\text{15
16. Problem 17-60 Benzyl chloride can be converted into benzalde
Problem 17-60 Benzyl chloride can be converted into benzalde
17. Problem 17-64 p-Nitrophenol and 2,6-dimethyl-4-nitrophenol b
Problem 17-64 p-Nitrophenol and 2,6-dimethyl-4-nitrophenol b
18. Problem 17-68 2,3-Dimethyl-2,3-butanediol has the common nam
Problem 17-68 2,3-Dimethyl-2,3-butanediol has the common nam
19. Problem 17-72 Identify the reagents a–f in the following sch
Problem 17-72 Identify the reagents a–f in the following sch
20. Key Terms
Key Terms
21. - phenoxide ion ArO– - protecting group - quinone
- phenoxide ion ArO– - protecting group - quinone
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