Organic Chemistry · free preview

Chapter 17: Review and Practice

In previous chapters, we focused on developing general ideas of organic reactivity, looking at the chemistry of hydrocarbons and alkyl halides and seeing some of the tools used in structural studies. With that accomplished, we have now begu

1. In previous chapters, we focused on developing general ideas

In previous chapters, we focused on developing general ideas

2. Phenols are aromatic counterparts of alcohols but are more a

Phenols are aromatic counterparts of alcohols but are more a

3. Chemistry Matters — Ethanol: Chemical, Drug, and Poison

Chemistry Matters — Ethanol: Chemical, Drug, and Poison

4. Ethanol metabolism occurs mainly in the liver and proceeds b

Ethanol metabolism occurs mainly in the liver and proceeds b

5. Summary of Reactions

Summary of Reactions

6. Additional Problems

Additional Problems

7. Problem 17-24 Name and assign R or S stereochemistry to the

Problem 17-24 Name and assign R or S stereochemistry to the

8. Problem 17-28 Treatment of the following epoxide with aqueou

Problem 17-28 Treatment of the following epoxide with aqueou

9. Problem 17-32 (a) (b) (c) Problem 17-33 (a) (b) (c) Problem

Problem 17-32 (a) (b) (c) Problem 17-33 (a) (b) (c) Problem

10. Problem 17-36 (a) (b) (c) Problem 17-37 (a) (b) (c) (d) (e)

Problem 17-36 (a) (b) (c) Problem 17-37 (a) (b) (c) (d) (e)

11. Problem 17-40 Bombykol, the sex pheromone secreted by the fe

Problem 17-40 Bombykol, the sex pheromone secreted by the fe

12. Problem 17-44 (a) 2-Methyl-2-propanol 2-Methyl-2-propanol (b

Problem 17-44 (a) 2-Methyl-2-propanol 2-Methyl-2-propanol (b

13. Problem 17-48 (a) Acetophenone (PhCOCH_{\text{3}}) cetopheno

Problem 17-48 (a) Acetophenone (PhCOCH_{\text{3}}) cetopheno

14. Problem 17-52 (a) C_{\text{5}}H_{\text{12}}O _{\text{5}}H_{\

Problem 17-52 (a) C_{\text{5}}H_{\text{12}}O _{\text{5}}H_{\

15. Problem 17-56 Propose a structure for a compound C_{\text{15

Problem 17-56 Propose a structure for a compound C_{\text{15

16. Problem 17-60 Benzyl chloride can be converted into benzalde

Problem 17-60 Benzyl chloride can be converted into benzalde

17. Problem 17-64 p-Nitrophenol and 2,6-dimethyl-4-nitrophenol b

Problem 17-64 p-Nitrophenol and 2,6-dimethyl-4-nitrophenol b

18. Problem 17-68 2,3-Dimethyl-2,3-butanediol has the common nam

Problem 17-68 2,3-Dimethyl-2,3-butanediol has the common nam

19. Problem 17-72 Identify the reagents a–f in the following sch

Problem 17-72 Identify the reagents a–f in the following sch

20. Key Terms

Key Terms

21. - phenoxide ion ArO– - protecting group - quinone

  • phenoxide ion ArO– - protecting group - quinone

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