Organic Chemistry · free preview
Chapter 18: Review and Practice
This chapter has finished the coverage of functional groups with C–O and C–S single bonds, focusing primarily on ethers, epoxides, thiols, and sulfides. Ethers are compounds that have two organic groups bonded to the same oxygen atom, ROR′.
1. This chapter has finished the coverage of functional groups
This chapter has finished the coverage of functional groups
2. Chemistry Matters — Epoxy Resins and Adhesives
Chemistry Matters — Epoxy Resins and Adhesives
3. When an epoxide is to be used, a basic curing agent such as
When an epoxide is to be used, a basic curing agent such as
4. Summary of Reactions
Summary of Reactions
5. Additional Problems
Additional Problems
6. Problem 18-23 (a) (b) Problem 18-24 (a) (b) Problem 18-25 (a
Problem 18-23 (a) (b) Problem 18-24 (a) (b) Problem 18-25 (a
7. Problem 18-27 (a) (b) Problem 18-28 (a) (b) Problem 18-29 In
Problem 18-27 (a) (b) Problem 18-28 (a) (b) Problem 18-29 In
8. Problem 18-31 Treatment of 1,1-diphenyl-1,2-epoxyethane with
Problem 18-31 Treatment of 1,1-diphenyl-1,2-epoxyethane with
9. Problem 18-35 The herbicide acifluorfen can be prepared by a
Problem 18-35 The herbicide acifluorfen can be prepared by a
10. Problem 18-39 Give IUPAC names for the following structures:
Problem 18-39 Give IUPAC names for the following structures:
11. Problem 18-43 Treatment of trans-2-chlorocyclohexanol with N
Problem 18-43 Treatment of trans-2-chlorocyclohexanol with N
12. Problem 18-47 Write the mechanism of the hydrolysis of cis-5
Problem 18-47 Write the mechanism of the hydrolysis of cis-5
13. Problem 18-51 Epoxides are reduced by treatment with lithium
Problem 18-51 Epoxides are reduced by treatment with lithium
14. Problem 18-55 (a) C_{\text{5}}H_{\text{12}}S (An –SH proton
Problem 18-55 (a) C_{\text{5}}H_{\text{12}}S (An –SH proton
15. Problem 18-59 Meerwein’s reagent, triethyloxonium tetrafluor
Problem 18-59 Meerwein’s reagent, triethyloxonium tetrafluor
16. Problem 18-63 Disparlure, C_{\text{19}}H_{\text{38}}O, is a
Problem 18-63 Disparlure, C_{\text{19}}H_{\text{38}}O, is a
17. Problem 18-67 (a) C_{\text{4}}H_{\text{10}}O_{\text{2}} _{\t
Problem 18-67 (a) C_{\text{4}}H_{\text{10}}O_{\text{2}} _{\t
18. Key Terms
Key Terms
19. - mercapto group - sulfide (R–S–R′) - sulfone - sulfonium io
- mercapto group - sulfide (R–S–R′) - sulfone - sulfonium io
20. - sulfoxide - thiol - thiolate ion (RS–) - Williamson ether
- sulfoxide - thiol - thiolate ion (RS–) - Williamson ether
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