Organic Chemistry · free preview

19.13 Conjugate Nucleophilic Addition to α,β‑Unsaturated Aldehydes and Ketones

All the reactions we’ve been discussing to this point have involved the addition of a nucleophile directly to the carbonyl group, a so-called 1,2-addition. Closely related to this direct addition is t

1. All the reactions we’ve been discussing to this point have i

All the reactions we’ve been discussing to this point have i

2. As noted, conjugate addition of a nucleophile to the β carbo

As noted, conjugate addition of a nucleophile to the β carbo

3. Conjugate Addition of Amines

Conjugate Addition of Amines

4. Conjugate Addition of Water

Conjugate Addition of Water

5. Conjugate Addition of Alkyl Groups: Organocopper Reactions

Conjugate Addition of Alkyl Groups: Organocopper Reactions

6. Primary, secondary, and even tertiary alkyl groups undergo t

Primary, secondary, and even tertiary alkyl groups undergo t

7. Part 7

Part 7

8. Worked Example 19.4: Using a Conjugate Addition Reaction

Worked Example 19.4: Using a Conjugate Addition Reaction

9. Problem 19-21 Treatment of 2-cyclohexenone with HCN/KCN yiel

Problem 19-21 Treatment of 2-cyclohexenone with HCN/KCN yiel

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