Chapter 24: Review and Practice

We’ve now seen all the common functional groups that occur i

Arylamines are prepared by nitration of an aromatic ring fol

Chemistry Matters — Green Chemistry II: Ionic Liquids

Ionic liquids have several important features that make them

The first commercial process using an ionic liquid catalyst

Summary of Reactions

Additional Problems

Problem 24-30 (a) (b) Problem 24-31 (a) (b) Problem 24-32 (a

Problem 24-34 The diazotization of aniline first involves th

Problem 24-38 Chlorophyll, heme, vitamin B_{\text{12}}, and

Problem 24-42 One of the reactions used in determining the s

Problem 24-46 One step in the biosynthesis of morphine is th

Problem 24-50 Although pyrrole is a much weaker base than mo

Problem 24-54 (a) Pentanamide entanamide (b) Butylamine utyl

Problem 24-58 How might a reductive amination be used to syn

Problem 24-62 (a) (b) (c) Problem 24-63 (a) (b) (c) Problem

Problem 24-66 (a) C_{\text{3}}H_{\text{9}}NO _{\text{3}}H_{\

Problem 24-70 Protonation of an amide using strong acid occu

Problem 24-74 Tetracaine is a substance used as a spinal ane

Problem 24-78 Coniine, C_{\text{8}}H_{\text{17}}N, is the to

Problem 24-82 Cyclooctatetraene was first synthesized in 191

Key Terms

• Curtius rearrangement - Gabriel amine synthesis - heterocy

• Hofmann rearrangement - imide (O=C–N–C=OO=C–N–C=O) - prima

• reductive amination - Sandmeyer reaction - secondary amine