Organic Chemistry · free preview

25.6 Reactions of Monosaccharides

Because monosaccharides have only two kinds of functional groups, hydroxyls and carbonyls, most of the chemistry of monosaccharides is the familiar chemistry of these two groups. As we’ve seen, alcoho

1. Because monosaccharides have only two kinds of functional gr

Because monosaccharides have only two kinds of functional gr

2. Ester and Ether Formation

Ester and Ether Formation

3. Problem 25-16 Draw the products you would obtain by reaction

Problem 25-16 Draw the products you would obtain by reaction

4. Glycoside Formation

Glycoside Formation

5. Glycosides are named by first citing the alkyl group and the

Glycosides are named by first citing the alkyl group and the

6. Although the Koenigs–Knorr reaction appears to involve a sim

Although the Koenigs–Knorr reaction appears to involve a sim

7. Biological Ester Formation: Phosphorylation

Biological Ester Formation: Phosphorylation

8. Reduction of Monosaccharides

Reduction of Monosaccharides

9. Problem 25-18 Reduction of L-gulose with NaBH_{\text{4}} lea

Problem 25-18 Reduction of L-gulose with NaBH_{\text{4}} lea

10. Oxidation of Monosaccharides

Oxidation of Monosaccharides

11. If warm, dilute HNO_{\text{3}} (nitric acid) is used as the

If warm, dilute HNO_{\text{3}} (nitric acid) is used as the

12. Problem 25-19 D-Glucose yields an optically active aldaric a

Problem 25-19 D-Glucose yields an optically active aldaric a

13. Chain Lengthening: The Kiliani–Fischer Synthesis

Chain Lengthening: The Kiliani–Fischer Synthesis

14. Problem 25-21 What product(s) would you expect from Kiliani–

Problem 25-21 What product(s) would you expect from Kiliani–

15. Chain Shortening: The Wohl Degradation

Chain Shortening: The Wohl Degradation

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