Organic Chemistry · free preview

4.8 Conformations of Disubstituted Cyclohexanes

Monosubstituted cyclohexanes are always more stable with their substituent in an equatorial position, but the situation with disubstituted cyclohexanes is more complex because the steric effects of bo

1. Monosubstituted cyclohexanes are always more stable with the

Monosubstituted cyclohexanes are always more stable with the

2. In trans-1,2-dimethylcyclohexane, the two methyl groups are

In trans-1,2-dimethylcyclohexane, the two methyl groups are

3. A summary of the various axial and equatorial relationships

A summary of the various axial and equatorial relationships

4. Part 4

Part 4

5. Worked Example 4.3: Drawing the Most Stable Conformation of a Substituted Cycloh

Worked Example 4.3: Drawing the Most Stable Conformation of a Substituted Cycloh

6. In the conformation on the left, the tert-butyl group is equ

In the conformation on the left, the tert-butyl group is equ

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