Organic Chemistry · 免费预览

第 1 章:复习与练习

本章的目的是让你快速入门——复习一些关于原子、键和分子几何构型的想法。正如我们所看到的,有机化学是研究碳化合物的学科。尽管将化学划分为有机化学和无机化学 c

1. The purpose of this chapter has been to get you up to speed—

The purpose of this chapter has been to get you up to speed—

2. Organic molecules are usually drawn using either condensed s

Organic molecules are usually drawn using either condensed s

3. Chemistry Matters — Organic Foods: Risk versus Benefit

Chemistry Matters — Organic Foods: Risk versus Benefit

4. How can the potential hazards from a chemical like atrazine

How can the potential hazards from a chemical like atrazine

5. Additional Problems

Additional Problems

6. Part 6

Part 6

7. Part 7

Part 7

8. Part 8

Part 8

9. Part 9

Part 9

10. Problem 1-32 Oxaloacetic acid, an important intermediate in

Problem 1-32 Oxaloacetic acid, an important intermediate in

11. Problem 1-34 What is the hybridization of each carbon atom i

Problem 1-34 What is the hybridization of each carbon atom i

12. Problem 1-38 Propose structures for molecules that meet the

Problem 1-38 Propose structures for molecules that meet the

13. Problem 1-42 How many hydrogens are bonded to each carbon at

Problem 1-42 How many hydrogens are bonded to each carbon at

14. Problem 1-46 Allene, H_{\text{2}}C\text{=}C\text{=}CH_{\text

Problem 1-46 Allene, H_{\text{2}}C\text{=}C\text{=}CH_{\text

15. Problem 1-50 A carbanion is a species that contains a negati

Problem 1-50 A carbanion is a species that contains a negati

16. Problem 1-54 Two different substances have the formula C_{\t

Problem 1-54 Two different substances have the formula C_{\t

17. Key Terms

Key Terms

18. - bond length - bond strength - bonding MO - condensed struc

  • bond length - bond strength - bonding MO - condensed struc

19. - covalent bond - electron shell - electron-dot structure -

  • covalent bond - electron shell - electron-dot structure -

20. - Hund’s rule - ionic bond - isotope - Kekulé structure

  • Hund’s rule - ionic bond - isotope - Kekulé structure

21. - Lewis structure - line-bond structure - lone-pair electron

  • Lewis structure - line-bond structure - lone-pair electron

22. - molecular orbital (MO) theory - molecule - node - nonbondi

  • molecular orbital (MO) theory - molecule - node - nonbondi

23. - orbital - organic chemistry - Pauli exclusion principle -

  • orbital - organic chemistry - Pauli exclusion principle -

24. - sigma (σ) bond - skeletal structure - sp hybrid orbital -

  • sigma (σ) bond - skeletal structure - sp hybrid orbital -

25. - sp3 hybrid orbital - valence bond (VB) theory - valence sh

  • sp3 hybrid orbital - valence bond (VB) theory - valence sh

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