Organic Chemistry · 免费预览

第 15 章:复习与实践

芳香环是许多生物结构的常见组成部分,在核酸化学和若干氨基酸的化学中尤为重要。在本章中,我们已经了解了芳香族化合物如何以及为何不同于

1. Aromatic rings are a common part of many biological structur

Aromatic rings are a common part of many biological structur

2. Aromatic compounds have the following characteristics: - Aro

Aromatic compounds have the following characteristics: - Aro

3. Chemistry Matters — Aspirin, NSAIDs, and COX-2 Inhibitors

Chemistry Matters — Aspirin, NSAIDs, and COX-2 Inhibitors

4. Although extraordinary in its effect, aspirin is also more d

Although extraordinary in its effect, aspirin is also more d

5. Medicinal chemists have therefore devised a number of drugs

Medicinal chemists have therefore devised a number of drugs

6. Additional Problems

Additional Problems

7. Part 7

Part 7

8. Part 8

Part 8

9. Part 9

Part 9

10. Part 10

Part 10

11. Problem 15-27 Look at the five resonance structures for phen

Problem 15-27 Look at the five resonance structures for phen

12. Problem 15-28 In 1932, A. A. Levine and A. G. Cole studied t

Problem 15-28 In 1932, A. A. Levine and A. G. Cole studied t

13. Problem 15-32 Cycloheptatrienone is stable, but cyclopentadi

Problem 15-32 Cycloheptatrienone is stable, but cyclopentadi

14. Problem 15-36 Pentalene is a most elusive molecule that has

Problem 15-36 Pentalene is a most elusive molecule that has

15. Problem 15-40 What is the structure of a hydrocarbon that ha

Problem 15-40 What is the structure of a hydrocarbon that ha

16. Problem 15-44 N-Phenylsydnone, so-named because it was first

Problem 15-44 N-Phenylsydnone, so-named because it was first

17. Problem 15-48 Propose a structure for a molecule C_{\text{14

Problem 15-48 Propose a structure for a molecule C_{\text{14

18. Problem 15-52 The substitution reaction of toluene with Br_{

Problem 15-52 The substitution reaction of toluene with Br_{

19. Problem 15-56 Compounds called azo dyes are the major source

Problem 15-56 Compounds called azo dyes are the major source

20. Key Terms

Key Terms

21. - degenerate orbitals - heterocycle - Hückel 4n + 2 rule - m

  • degenerate orbitals - heterocycle - Hückel 4n + 2 rule - m

22. - ortho (o) - para (p) - phenyl group - ring-current

  • ortho (o) - para (p) - phenyl group - ring-current

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