Organic Chemistry · 免费预览
第 15 章:复习与实践
芳香环是许多生物结构的常见组成部分,在核酸化学和若干氨基酸的化学中尤为重要。在本章中,我们已经了解了芳香族化合物如何以及为何不同于
1. Aromatic rings are a common part of many biological structur
Aromatic rings are a common part of many biological structur
2. Aromatic compounds have the following characteristics: - Aro
Aromatic compounds have the following characteristics: - Aro
3. Chemistry Matters — Aspirin, NSAIDs, and COX-2 Inhibitors
Chemistry Matters — Aspirin, NSAIDs, and COX-2 Inhibitors
4. Although extraordinary in its effect, aspirin is also more d
Although extraordinary in its effect, aspirin is also more d
5. Medicinal chemists have therefore devised a number of drugs
Medicinal chemists have therefore devised a number of drugs
6. Additional Problems
Additional Problems
7. Part 7
Part 7
8. Part 8
Part 8
9. Part 9
Part 9
10. Part 10
Part 10
11. Problem 15-27 Look at the five resonance structures for phen
Problem 15-27 Look at the five resonance structures for phen
12. Problem 15-28 In 1932, A. A. Levine and A. G. Cole studied t
Problem 15-28 In 1932, A. A. Levine and A. G. Cole studied t
13. Problem 15-32 Cycloheptatrienone is stable, but cyclopentadi
Problem 15-32 Cycloheptatrienone is stable, but cyclopentadi
14. Problem 15-36 Pentalene is a most elusive molecule that has
Problem 15-36 Pentalene is a most elusive molecule that has
15. Problem 15-40 What is the structure of a hydrocarbon that ha
Problem 15-40 What is the structure of a hydrocarbon that ha
16. Problem 15-44 N-Phenylsydnone, so-named because it was first
Problem 15-44 N-Phenylsydnone, so-named because it was first
17. Problem 15-48 Propose a structure for a molecule C_{\text{14
Problem 15-48 Propose a structure for a molecule C_{\text{14
18. Problem 15-52 The substitution reaction of toluene with Br_{
Problem 15-52 The substitution reaction of toluene with Br_{
19. Problem 15-56 Compounds called azo dyes are the major source
Problem 15-56 Compounds called azo dyes are the major source
20. Key Terms
Key Terms
21. - degenerate orbitals - heterocycle - Hückel 4n + 2 rule - m
- degenerate orbitals - heterocycle - Hückel 4n + 2 rule - m
22. - ortho (o) - para (p) - phenyl group - ring-current
- ortho (o) - para (p) - phenyl group - ring-current