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第16章：复习与练习
本章我们继续讨论芳香分子，将重点转向反应。特别地，我们考察了芳香结构与反应性之间的关系，这一关系对于理解
1. We’ve continued the coverage of aromatic molecules in this c
We’ve continued the coverage of aromatic molecules in this c
2. Substituents on the benzene ring affect both the reactivity
Substituents on the benzene ring affect both the reactivity
3. Chemistry Matters — Combinatorial Chemistry
Chemistry Matters — Combinatorial Chemistry
4. In split synthesis, the initial reactant is again linked to
In split synthesis, the initial reactant is again linked to
5. Summary of Reactions
Summary of Reactions
6. Additional Problems
Additional Problems
7. Part 7
Part 7
8. Part 8
Part 8
9. Part 9
Part 9
10. Part 10
Part 10
11. Problem 16-38 Benzenediazonium carboxylate decomposes when h
Problem 16-38 Benzenediazonium carboxylate decomposes when h
12. Problem 16-39 4-Chloropyridine undergoes reaction with dimet
Problem 16-39 4-Chloropyridine undergoes reaction with dimet
13. Problem 16-43 Benzyl bromide is converted into benzaldehyde
Problem 16-43 Benzyl bromide is converted into benzaldehyde
14. Problem 16-47 Predict the major product(s) of nitration of t
Problem 16-47 Predict the major product(s) of nitration of t
15. Problem 16-51 Predict the major product(s) you would obtain
Problem 16-51 Predict the major product(s) you would obtain
16. Problem 16-55 How would you synthesize the following substan
Problem 16-55 How would you synthesize the following substan
17. Problem 16-59 At what position and on what ring do you expec
Problem 16-59 At what position and on what ring do you expec
18. Problem 16-63 Would you expect the Friedel–Crafts reaction o
Problem 16-63 Would you expect the Friedel–Crafts reaction o
19. Problem 16-67 Draw resonance structures of the intermediate
Problem 16-67 Draw resonance structures of the intermediate
20. Problem 16-71 How would you synthesize the following compoun
Problem 16-71 How would you synthesize the following compoun
21. Problem 16-75 Phenols (ArOH) are relatively acidic, and the
Problem 16-75 Phenols (ArOH) are relatively acidic, and the
22. Key Terms
Key Terms
23. - combinatorial chemistry - electrophilic aromatic substitut
- combinatorial chemistry - electrophilic aromatic substitut
24. - nucleophilic aromatic substitution - resonance effect
- nucleophilic aromatic substitution - resonance effect