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17.2 醇和酚的性质
醇和酚在氧原子周围的几何构型与水几乎相同。R–O–H 键角约为四面体值(例如甲醇中为 108.5°),而氧原子
1. Alcohols and phenols have nearly the same geometry around th
Alcohols and phenols have nearly the same geometry around th
2. As weak acids, they dissociate slightly in dilute aqueous so
As weak acids, they dissociate slightly in dilute aqueous so
3. Compounds with a smaller K_{\text{a}} and larger pK_{\text{a
Compounds with a smaller K_{\text{a}} and larger pK_{\text{a
4. Inductive effects (Section 16.4) are also important in deter
Inductive effects (Section 16.4) are also important in deter
5. Phenols are about a million times more acidic than alcohols
Phenols are about a million times more acidic than alcohols
6. Substituted phenols can be either more acidic or less acidic
Substituted phenols can be either more acidic or less acidic
7. Part 7
Part 7
8. Worked Example 17.1: Predicting the Relative Acidity of a Substituted Phenol
Worked Example 17.1: Predicting the Relative Acidity of a Substituted Phenol
9. Part 9
Part 9