Organic Chemistry · 免费预览
第17章：复习与练习
在前几章中，我们着重建立了有机反应性的总体概念，考察了烃和卤代烷的化学，并了解了一些用于结构研究的工具。在此基础上，我们现在已经开
1. In previous chapters, we focused on developing general ideas
In previous chapters, we focused on developing general ideas
2. Phenols are aromatic counterparts of alcohols but are more a
Phenols are aromatic counterparts of alcohols but are more a
3. Chemistry Matters — Ethanol: Chemical, Drug, and Poison
Chemistry Matters — Ethanol: Chemical, Drug, and Poison
4. Ethanol metabolism occurs mainly in the liver and proceeds b
Ethanol metabolism occurs mainly in the liver and proceeds b
5. Summary of Reactions
Summary of Reactions
6. Additional Problems
Additional Problems
7. Part 7
Part 7
8. Part 8
Part 8
9. Part 9
Part 9
10. Part 10
Part 10
11. Part 11
Part 11
12. Part 12
Part 12
13. Problem 17-34 The trimethylsilyl (TMS) protecting group is o
Problem 17-34 The trimethylsilyl (TMS) protecting group is o
14. Problem 17-38 Draw and name the eight isomeric alcohols with
Problem 17-38 Draw and name the eight isomeric alcohols with
15. Problem 17-42 What Grignard reagent and what carbonyl compou
Problem 17-42 What Grignard reagent and what carbonyl compou
16. Problem 17-46 What products would you obtain from reaction o
Problem 17-46 What products would you obtain from reaction o
17. Problem 17-50 What products would you expect to obtain from
Problem 17-50 What products would you expect to obtain from
18. Problem 17-54 The ^{\text{1}}H NMR spectrum shown is that of
Problem 17-54 The ^{\text{1}}H NMR spectrum shown is that of
19. Problem 17-58 Benzoquinone is an excellent dienophile in the
Problem 17-58 Benzoquinone is an excellent dienophile in the
20. Problem 17-62 Testosterone is one of the most important male
Problem 17-62 Testosterone is one of the most important male
21. Problem 17-66 Compound A, C_{\text{5}}H_{\text{10}}O, is one
Problem 17-66 Compound A, C_{\text{5}}H_{\text{10}}O, is one
22. Problem 17-70 Propose a synthesis of bicyclohexylidene, star
Problem 17-70 Propose a synthesis of bicyclohexylidene, star
23. Problem 17-74 Propose structures for alcohols that have the
Problem 17-74 Propose structures for alcohols that have the
24. Key Terms
Key Terms
25. - phenoxide ion ArO– - protecting group - quinone
- phenoxide ion ArO– - protecting group - quinone