Organic Chemistry · 免费预览
第18章：复习与练习
本章完成了对含C–O和C–S单键官能团的介绍，主要关注醚、环氧化物、硫醇和硫化物。醚是同一个氧原子上连接两个有机基团的化合物，ROR′。
1. This chapter has finished the coverage of functional groups
This chapter has finished the coverage of functional groups
2. Chemistry Matters — Epoxy Resins and Adhesives
Chemistry Matters — Epoxy Resins and Adhesives
3. When an epoxide is to be used, a basic curing agent such as
When an epoxide is to be used, a basic curing agent such as
4. Summary of Reactions
Summary of Reactions
5. Additional Problems
Additional Problems
6. Part 6
Part 6
7. Part 7
Part 7
8. Part 8
Part 8
9. Part 9
Part 9
10. Part 10
Part 10
11. Part 11
Part 11
12. Problem 18-33 When 2-methyl-2,5-pentanediol is treated with
Problem 18-33 When 2-methyl-2,5-pentanediol is treated with
13. Problem 18-37 Propose a mechanism to account for the followi
Problem 18-37 Propose a mechanism to account for the followi
14. Problem 18-41 How would you prepare the following compounds
Problem 18-41 How would you prepare the following compounds
15. Problem 18-45 How would you carry out the following transfor
Problem 18-45 How would you carry out the following transfor
16. Problem 18-49 Acid-catalyzed hydrolysis of a 1,2-epoxycycloh
Problem 18-49 Acid-catalyzed hydrolysis of a 1,2-epoxycycloh
17. Problem 18-53 The red fox (Vulpes vulpes) uses a chemical co
Problem 18-53 The red fox (Vulpes vulpes) uses a chemical co
18. Problem 18-57 How would you synthesize anethole (Problem 18-
Problem 18-57 How would you synthesize anethole (Problem 18-
19. Problem 18-61 Grignard reagents react with oxetane, a four-m
Problem 18-61 Grignard reagents react with oxetane, a four-m
20. Problem 18-65 How would you prepare o-hydroxyphenylacetaldeh
Problem 18-65 How would you prepare o-hydroxyphenylacetaldeh
21. Key Terms
Key Terms
22. - mercapto group - sulfide (R–S–R′) - sulfone - sulfonium io
- mercapto group - sulfide (R–S–R′) - sulfone - sulfonium io
23. - sulfoxide - thiol - thiolate ion (RS–) - Williamson ether
- sulfoxide - thiol - thiolate ion (RS–) - Williamson ether