Organic Chemistry · 免费预览
第 22 章：复习与练习
羰基化合物的 α-取代反应通过烯醇或烯醇负离子中间体进行，是羰基化学中四种基本反应类型之一。
1. The α-substitution reaction of a carbonyl compound through e
The α-substitution reaction of a carbonyl compound through e
2. Chemistry Matters — Barbiturates
Chemistry Matters — Barbiturates
3. In addition to their prescribed medical uses, many barbitura
In addition to their prescribed medical uses, many barbitura
4. Summary of Reactions
Summary of Reactions
5. Additional Problems
Additional Problems
6. Part 6
Part 6
7. Part 7
Part 7
8. Part 8
Part 8
9. Part 9
Part 9
10. Part 10
Part 10
11. Problem 22-31 The Favorskii reaction involves treatment of a
Problem 22-31 The Favorskii reaction involves treatment of a
12. Problem 22-32 Treatment of a cyclic ketone with diazomethane
Problem 22-32 Treatment of a cyclic ketone with diazomethane
13. Problem 22-36 Heating carvone with aqueous sulfuric acid con
Problem 22-36 Heating carvone with aqueous sulfuric acid con
14. Problem 22-40 Base treatment of the following α,β-unsaturate
Problem 22-40 Base treatment of the following α,β-unsaturate
15. Problem 22-44 Which, if any, of the following compounds can
Problem 22-44 Which, if any, of the following compounds can
16. Problem 22-48 How might you convert geraniol into either eth
Problem 22-48 How might you convert geraniol into either eth
17. Problem 22-52 Would you expect optically active (S)-3-methyl
Problem 22-52 Would you expect optically active (S)-3-methyl
18. Problem 22-56 How would you synthesize the following compoun
Problem 22-56 How would you synthesize the following compoun
19. Problem 22-60 Ketones react slowly with benzeneselenenyl chl
Problem 22-60 Ketones react slowly with benzeneselenenyl chl
20. Key Terms
Key Terms
21. - enolate ion - malonic ester synthesis - tautomer
- enolate ion - malonic ester synthesis - tautomer