Organic Chemistry · 免费预览
第23章：复习与练习
在本章中，我们讨论了常见羰基反应的第四个也是最后一个——羰基缩合。羰基缩合反应发生在两个羰基伙伴之间，并涉及亲核加成和α-
1. In this chapter, we’ve discussed the fourth and last of the
In this chapter, we’ve discussed the fourth and last of the
2. The conjugate addition of a carbon nucleophile to an α,β-uns
The conjugate addition of a carbon nucleophile to an α,β-uns
3. Chemistry Matters — A Prologue to Metabolism
Chemistry Matters — A Prologue to Metabolism
4. Glycolysis is a ten-step process that begins with isomerizat
Glycolysis is a ten-step process that begins with isomerizat
5. These few examples are only an introduction; we’ll look at s
These few examples are only an introduction; we’ll look at s
6. Summary of Reactions
Summary of Reactions
7. Additional Problems
Additional Problems
8. Part 8
Part 8
9. Part 9
Part 9
10. Part 10
Part 10
11. Part 11
Part 11
12. Part 12
Part 12
13. Part 13
Part 13
14. Problem 23-37 The amino acid leucine is biosynthesized from
Problem 23-37 The amino acid leucine is biosynthesized from
15. Problem 23-40 The following reaction involves a hydrolysis f
Problem 23-40 The following reaction involves a hydrolysis f
16. Problem 23-44 Propose a mechanism for the following base-cat
Problem 23-44 Propose a mechanism for the following base-cat
17. Problem 23-48 Which of the following compounds would you exp
Problem 23-48 Which of the following compounds would you exp
18. Problem 23-52 The major product formed by intramolecular ald
Problem 23-52 The major product formed by intramolecular ald
19. Problem 23-56 Cinnamaldehyde, the aromatic constituent of ci
Problem 23-56 Cinnamaldehyde, the aromatic constituent of ci
20. Problem 23-60 Ethyl dimethylacetoacetate reacts instantly at
Problem 23-60 Ethyl dimethylacetoacetate reacts instantly at
21. Problem 23-64 The Stork enamine reaction and the intramolecu
Problem 23-64 The Stork enamine reaction and the intramolecu
22. Problem 23-68 The following reactions are unlikely to provid
Problem 23-68 The following reactions are unlikely to provid
23. Problem 23-72 The third and fourth steps in the synthesis of
Problem 23-72 The third and fourth steps in the synthesis of
24. Key Terms
Key Terms
25. - Michael reaction - Robinson annulation reaction - Stork en
- Michael reaction - Robinson annulation reaction - Stork en