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第24章：复习与练习
现在我们已经见过有机化学和生物化学中出现的所有常见官能团。在这些基团中，胺是最丰富的之一，并且具有最丰富的化学性质之一。除了蛋白质和核酸之外，大多
1. We’ve now seen all the common functional groups that occur i
We’ve now seen all the common functional groups that occur i
2. Arylamines are prepared by nitration of an aromatic ring fol
Arylamines are prepared by nitration of an aromatic ring fol
3. Chemistry Matters — Green Chemistry II: Ionic Liquids
Chemistry Matters — Green Chemistry II: Ionic Liquids
4. Ionic liquids have several important features that make them
Ionic liquids have several important features that make them
5. The first commercial process using an ionic liquid catalyst
The first commercial process using an ionic liquid catalyst
6. Summary of Reactions
Summary of Reactions
7. Additional Problems
Additional Problems
8. Part 8
Part 8
9. Part 9
Part 9
10. Part 10
Part 10
11. Part 11
Part 11
12. Part 12
Part 12
13. Problem 24-40 The antitumor antibiotic mitomycin C functions
Problem 24-40 The antitumor antibiotic mitomycin C functions
14. Problem 24-43 When an α-hydroxy amide is treated with Br_{\t
Problem 24-43 When an α-hydroxy amide is treated with Br_{\t
15. Problem 24-47 Name the following compounds: (a) Problem 24-4
Problem 24-47 Name the following compounds: (a) Problem 24-4
16. Problem 24-51 Histamine, whose release in the body triggers
Problem 24-51 Histamine, whose release in the body triggers
17. Problem 24-55 How would you prepare aniline from the followi
Problem 24-55 How would you prepare aniline from the followi
18. Problem 24-59 How would you convert aniline into each of the
Problem 24-59 How would you convert aniline into each of the
19. Problem 24-63 How would you prepare the following compounds
Problem 24-63 How would you prepare the following compounds
20. Problem 24-67 Draw the structure of the amine that produced
Problem 24-67 Draw the structure of the amine that produced
21. Problem 24-71 What is the structure of the compound with for
Problem 24-71 What is the structure of the compound with for
22. Problem 24-75 Atropine, C_{\text{17}}H_{\text{23}}NO_{\text{
Problem 24-75 Atropine, C_{\text{17}}H_{\text{23}}NO_{\text{
23. Problem 24-79 How would you synthesize coniine (Problem 24-7
Problem 24-79 How would you synthesize coniine (Problem 24-7
24. Problem 24-83 Propose structures for compounds that show the
Problem 24-83 Propose structures for compounds that show the
25. Key Terms
Key Terms
26. - Curtius rearrangement - Gabriel amine synthesis - heterocy
- Curtius rearrangement - Gabriel amine synthesis - heterocy
27. - Hofmann rearrangement - imide (O=C–N–C=OO=C–N–C=O) - prima
- Hofmann rearrangement - imide (O=C–N–C=OO=C–N–C=O) - prima
28. - reductive amination - Sandmeyer reaction - secondary amine
- reductive amination - Sandmeyer reaction - secondary amine