Organic Chemistry · 免费预览

第25章:复习与练习

既然我们已经了解了所有常见的官能团和反应类型,我们的重点就转向了生物分子的主要类别。碳水化合物是多羟基醛和多羟基酮。它们根据……进行分类

1. Now that we’ve now seen all the common functional groups and

Now that we’ve now seen all the common functional groups and

2. Chemistry Matters — Sweetness

Chemistry Matters — Sweetness

3. Acesulfame potassium, one of the more recently approved swee

Acesulfame potassium, one of the more recently approved swee

4. Summary of Reactions

Summary of Reactions

5. Additional Problems

Additional Problems

6. Part 6

Part 6

7. Part 7

Part 7

8. Part 8

Part 8

9. Part 9

Part 9

10. Part 10

Part 10

11. Problem 25-40 Draw the three-dimensional furanose form of as

Problem 25-40 Draw the three-dimensional furanose form of as

12. Problem 25-43 Draw Fischer projections for the two D aldohep

Problem 25-43 Draw Fischer projections for the two D aldohep

13. Problem 25-47 Draw D-ribulose in its five-membered cyclic β-

Problem 25-47 Draw D-ribulose in its five-membered cyclic β-

14. Problem 25-51 One of the D-2-ketohexoses is called sorbose.

Problem 25-51 One of the D-2-ketohexoses is called sorbose.

15. Problem 25-55 All aldoses exhibit mutarotation. For example,

Problem 25-55 All aldoses exhibit mutarotation. For example,

16. Problem 25-59 Draw the structure of L-galactose, and then an

Problem 25-59 Draw the structure of L-galactose, and then an

17. Problem 25-63 Isotrehalose and neotrehalose are chemically s

Problem 25-63 Isotrehalose and neotrehalose are chemically s

18. Problem 25-67 The cyclitols are a group of carbocyclic sugar

Problem 25-67 The cyclitols are a group of carbocyclic sugar

19. Problem 25-71 Acetyl coenzyme A (acetyl CoA) is the key inte

Problem 25-71 Acetyl coenzyme A (acetyl CoA) is the key inte

20. Key Terms

Key Terms

21. - amino sugar - α anomer - β anomer - anomeric center

  • amino sugar - α anomer - β anomer - anomeric center

22. - anomer - carbohydrate - complex carbohydrate - D sugar

  • anomer - carbohydrate - complex carbohydrate - D sugar

23. - deoxy sugar - disaccharide - Fischer projection - furanose

  • deoxy sugar - disaccharide - Fischer projection - furanose

24. - glycoside - ketose - Kiliani–Fischer synthesis - Koenigs–K

  • glycoside - ketose - Kiliani–Fischer synthesis - Koenigs–K

25. - L sugar - monosaccharide - mutarotation - polysaccharide

  • L sugar - monosaccharide - mutarotation - polysaccharide

26. - pyranose - reducing sugar - simple sugar - uronic acid

  • pyranose - reducing sugar - simple sugar - uronic acid

27. - Wohl degradation

  • Wohl degradation

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