Organic Chemistry · 免费预览
31.2 聚合的立体化学：齐格勒–纳塔催化剂
尽管我们在第8.10节讨论链增长聚合物时没有指出这一点，但取代乙烯基单体的聚合可以生成在其链中含有大量手性中心的聚合物
1. Although we didn’t point it out when discussing chain-growth
Although we didn’t point it out when discussing chain-growth
2. {({CH}_3{CH}_2)}_3Al+{TiCl}_4\rightarrowA Ziegler–Natta cata
{({CH}_3{CH}_2)}_3Al+{TiCl}_4\rightarrowA Ziegler–Natta cata
3. The linear polyethylene produced by the Ziegler–Natta proces
The linear polyethylene produced by the Ziegler–Natta proces