Organic Chemistry · 免费预览
第6章：复习与练习
所有化学反应，无论是在实验室中还是在生物体内，都遵循相同的化学规则。要理解有机化学和生物化学，不仅需要知道发生了什么，还需要知道化学反应为什么发生以及如何发生。
1. All chemical reactions, whether in the laboratory or in livi
All chemical reactions, whether in the laboratory or in livi
2. The energy changes that take place during reactions can be d
The energy changes that take place during reactions can be d
3. Chemistry Matters — Where Do Drugs Come From?
Chemistry Matters — Where Do Drugs Come From?
4. Human testing takes, or should take, 5 to 7 years and is div
Human testing takes, or should take, 5 to 7 years and is div
5. Additional Problems
Additional Problems
6. Part 6
Part 6
7. Part 7
Part 7
8. Part 8
Part 8
9. Problem 6-28 Use curved arrows to show the flow of electrons
Problem 6-28 Use curved arrows to show the flow of electrons
10. Problem 6-31 Identify the likely electrophilic and nucleophi
Problem 6-31 Identify the likely electrophilic and nucleophi
11. Problem 6-35 Radical chlorination of pentane is a poor way t
Problem 6-35 Radical chlorination of pentane is a poor way t
12. Problem 6-39 Show the structure of the carbocation that woul
Problem 6-39 Show the structure of the carbocation that woul
13. Problem 6-43 Methoxide ion (CH_{\text{3}}O^{\text{−}}) react
Problem 6-43 Methoxide ion (CH_{\text{3}}O^{\text{−}}) react
14. Problem 6-47 Reaction of 2-methylpropene with HBr might, in
Problem 6-47 Reaction of 2-methylpropene with HBr might, in
15. Key Terms
Key Terms
16. - carbocation - electrophile - elimination reaction - enderg
- carbocation - electrophile - elimination reaction - enderg
17. - endothermic - enthalpy change (ΔH) - entropy change (ΔS) -
- endothermic - enthalpy change (ΔH) - entropy change (ΔS) -
18. - exergonic - exothermic - Gibbs free-energy change (ΔG) - h
- exergonic - exothermic - Gibbs free-energy change (ΔG) - h
19. - nucleophile - polar reaction - polarizability - radical
- nucleophile - polar reaction - polarizability - radical
20. - radical reaction - reaction coordinate - reaction intermed
- radical reaction - reaction coordinate - reaction intermed
21. - rearrangement reaction - substitution reaction - transitio
- rearrangement reaction - substitution reaction - transitio