Organic Chemistry · 免费预览
第 7 章：复习与练习
碳–碳双键存在于大多数有机和生物分子中，因此需要很好地理解它们的行为。在本章中，我们考察了烯烃立体异构的一些后果以及溴化的细节。
1. Carbon–carbon double bonds are present in most organic and b
Carbon–carbon double bonds are present in most organic and b
2. Tertiary (3°) > Secondary (2°) > Primary (1°) > Methyl R_{\t
Tertiary (3°) > Secondary (2°) > Primary (1°) > Methyl R_{\t
3. Chemistry Matters — Bioprospecting: Hunting for Natural Products
Chemistry Matters — Bioprospecting: Hunting for Natural Products
4. Where do these natural products come from, and how are they
Where do these natural products come from, and how are they
5. Additional Problems
Additional Problems
6. Part 6
Part 6
7. Part 7
Part 7
8. Part 8
Part 8
9. Part 9
Part 9
10. Part 10
Part 10
11. Problem 7-36 Loratadine, marketed as an antiallergy medicati
Problem 7-36 Loratadine, marketed as an antiallergy medicati
12. Problem 7-37 Name the following alkenes: (a) Problem 7-38 Dr
Problem 7-37 Name the following alkenes: (a) Problem 7-38 Dr
13. Problem 7-41 α-Farnesene is a constituent of the natural wax
Problem 7-41 α-Farnesene is a constituent of the natural wax
14. Problem 7-45 Rank the following sets of substituents accordi
Problem 7-45 Rank the following sets of substituents accordi
15. Problem 7-49 trans-2-Butene is more stable than cis-2-butene
Problem 7-49 trans-2-Butene is more stable than cis-2-butene
16. Problem 7-53 Tamoxifen, a drug used in the treatment of brea
Problem 7-53 Tamoxifen, a drug used in the treatment of brea
17. Problem 7-57 Predict the major product in each of the follow
Problem 7-57 Predict the major product in each of the follow
18. Problem 7-61 Allene (1,2-propadiene), H_{\text{2}}C\text{=}C
Problem 7-61 Allene (1,2-propadiene), H_{\text{2}}C\text{=}C
19. Problem 7-65 tert-Butyl esters [RCO_{\text{2}}C(CH_{\text{3}
Problem 7-65 tert-Butyl esters [RCO_{\text{2}}C(CH_{\text{3}
20. Problem 7-69 Draw an energy diagram for the addition of HBr
Problem 7-69 Draw an energy diagram for the addition of HBr
21. Key Terms
Key Terms
22. - E,Z system - electrophilic addition reaction - Hammond pos
- E,Z system - electrophilic addition reaction - Hammond pos
23. - hyperconjugation - Markovnikov’s rule - methylene group -
- hyperconjugation - Markovnikov’s rule - methylene group -
24. - unsaturated - vinyl group - Z configuration
- unsaturated - vinyl group - Z configuration