Organic Chemistry · 免费预览
第8章：复习与练习
在已具备理解有机反应所需背景知识的基础上，本章开始系统描述主要官能团。
1. With the background needed to understand organic reactions n
With the background needed to understand organic reactions n
2. Alkenes are reduced by addition of H_{\text{2}} in the prese
Alkenes are reduced by addition of H_{\text{2}} in the prese
3. Chemistry Matters — Terpenes: Naturally Occurring Alkenes
Chemistry Matters — Terpenes: Naturally Occurring Alkenes
4. Regardless of their apparent structural differences, all ter
Regardless of their apparent structural differences, all ter
5. Isoprene itself is not the true biological precursor of terp
Isoprene itself is not the true biological precursor of terp
6. Summary of Reactions
Summary of Reactions
7. Additional Problems
Additional Problems
8. Part 8
Part 8
9. Part 9
Part 9
10. Part 10
Part 10
11. Part 11
Part 11
12. Part 12
Part 12
13. Part 13
Part 13
14. Problem 8-36 Reaction of cyclohexene with mercury(II) acetat
Problem 8-36 Reaction of cyclohexene with mercury(II) acetat
15. Problem 8-39 Hydroboration of 2-methyl-2-pentene at 25 °C, f
Problem 8-39 Hydroboration of 2-methyl-2-pentene at 25 °C, f
16. Problem 8-43 Which reaction would you expect to be faster, a
Problem 8-43 Which reaction would you expect to be faster, a
17. Problem 8-47 Addition of HCl to 1-methoxycyclohexene yields
Problem 8-47 Addition of HCl to 1-methoxycyclohexene yields
18. Problem 8-51 In planning the synthesis of one compound from
Problem 8-51 In planning the synthesis of one compound from
19. Problem 8-55 When a single alkene monomer, such as ethylene,
Problem 8-55 When a single alkene monomer, such as ethylene,
20. Problem 8-59 Compound A, C_{\text{10}}H_{\text{18}}O, underg
Problem 8-59 Compound A, C_{\text{10}}H_{\text{18}}O, underg
21. Problem 8-63 Compound A has the formula C_{\text{8}}H_{\text
Problem 8-63 Compound A has the formula C_{\text{8}}H_{\text
22. Problem 8-67 Reaction of HBr with 3-methylcyclohexene yields
Problem 8-67 Reaction of HBr with 3-methylcyclohexene yields
23. Key Terms
Key Terms
24. - epoxide - glycol - halohydrin - hydroboration
- epoxide - glycol - halohydrin - hydroboration
25. - hydrogenated - hydroxylation - monomer - oxidation
- hydrogenated - hydroxylation - monomer - oxidation
26. - oxirane - oxymercuration–demercuration - ozonide - polymer
- oxirane - oxymercuration–demercuration - ozonide - polymer
27. - reduction - Simmons–Smith reaction - stereospecific - syn
- reduction - Simmons–Smith reaction - stereospecific - syn